Use of amine-aluminum chloride adducts as alkylation...

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252/30, 260/719.

B01D 11/04 (2006.01) B01D 53/14 (2006.01) C07C 7/152 (2006.01) C09K 15/32 (2006.01)

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CA 1155434

Abstract of the Disclosure In processes in which liquid sorbents that are solutions in an aromatic hydrocarbon or halogenated aromatic hydrocarbon Or a bimetallic salt complex having the generic formula MIMIIXn'Aromatic, wherein MI is a Group I-B metal, MII is a Group III-A metal, X is halogen, n is the sum of the valences of MI and MII, and Aromatic is a monocyclic aromatic hydrocarbon or halogenated aromatic hydrocarbon are used to separate complexible ligands from a gas feedstream that comprises an olefin having 2 or 3 carbon atoms, alkylation of the aromatic hydrocarbon or halogenated aromatic hydrocar- bon is inhibited by incorporating in the liquid sorbent from 8.5 mole percent to 30 mole percent, based on t? Group I-B metal in the liquid sorbent, of an amine-aluminum chloride adduct, such as ammonia-aluminum chloride adduct or pyridine- aluminum chloride adduct.

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