Use of low unsaturated polyether polyols in slabstock foam...

C - Chemistry – Metallurgy – 08 – G

Patent

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Details

C08G 18/48 (2006.01) C08G 18/72 (2006.01) C08J 9/12 (2006.01) C08K 5/54 (2006.01) C08L 75/08 (2006.01)

Patent

CA 2380301

The present invention discloses a method for the formation of and a flexible slabstock polyurethane foam having substantially improved indention force deflection and resilience characteristics while maintaining the other physical properties. The method comprises the steps of: forming a blend of three polyols, each having a plurality of ethylene oxide caps of from 5-25 % by weight based on weight of the polyol, by combining at least one polyether polyol having low unsaturation and a molecular weight no less than 4000 Daltons; at least one graft polyether polyol having an equivalennt weight no less than 1000 Daltons and a solids content of at least 28 %; and at least one polyether polyol having an unsaturation no greater than 0.018 meq/g KOH; providing at least one polyisocyanate component, a catalyst, 3-7 % by weight of water as a blowing magnet; and combining the components to form a slabstock polyurethane foam.

Cette invention concerne un procédé de fabrication de plaques de mousse de poyluréthane élastique qui présentent des caractéristiques améliorées en termes de flexion au foulage et de résilience tout en conservant leurs autres propriétés physiques. Ce procédé consiste à : réaliser un mélange de trois polyols qui présentent chacun plusieurs terminaisons d'oxyde d'éthylène correspondant en poids à 5-25 % du polyol, ceci en combinant au moins un polyol de polyéther à faible taux d'insaturation et au poids moléculaire d'au moins 4000 Daltons, au moins un polyol de polyéther greffé ayant un poids équivalent d'au moins 1000 Daltons et une teneur en solides d'au moins 28 %, et au moins un polyol de polyéther ayant un taux d'insaturation de 0,018 meq/g KOH maximum; apporter au moins un composant polyisocyanate, un catalyseur, de 3 à7 % en poids d'eau comme agent gonflant ; et à combiner ces composants pour former une mousse de polyuréthane en plaque.

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