Use of pyrazole derivatives containing hydrophobic radicals...

C - Chemistry – Metallurgy – 07 – D

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C07D 231/12 (2006.01) C05G 3/08 (2006.01) C07D 231/16 (2006.01) C07D 521/00 (2006.01)

Patent

CA 2208529

Disclosed is the use as nitrification inhibitors of pyrazole derivatives of formula (I), or salts thereof, in which the groups R1-R4 have the following meanings: R1, R2 and R3 represent C1-C20 alkyl, C3-C8 cycloalkyl, C5-C20 aryl or alkyl aryl (these four groups can be singly or doubly substituted by a halogen and/or hydroxyl), and halogen, nitro or hydrogen; and R4 represents either (a) C6-C20 alkyl, one or two hydrogen atoms being optionally substituted by a halogen; or (b) C1-C20 alkyl. In the latter case, 1-4 hydrogen atoms can be substituted by a group of formula (II), in which R5, R6, and R7 represent C1-C20 alkyl, C3-C8 cycloalkyl, C5-C20 aryl or alkyl aryl (these four groups can be singly or doubly substituted by a halogen and/or hydroxyl), as well as halogen, nitro or hydrogen; and 1 or two hydrogen atoms are optionally substituted by a halogen.

L'invention concerne l'utilisation, sous forme d'inhibiteurs de nitrification, de dérivés de pyrazol de formule (I) ou de leurs sels, formule dans laquelle les radicaux R?1¿ à R?4¿ ont la signification suivante: R?1¿, R?2¿ et R?3¿ représentent alkyle C¿1?-C¿20?, cycloalkyle C¿3?-C¿8?, aryle C¿5?-C¿20? ou alkylaryl (ces quatre radicaux pouvant être substitués une ou deux fois par halogène et/ou hydroxyle), ainsi que halogène, nitro ou hydrogène; et R?4¿ représente soit a) alkyle C¿6?-C¿20?, le cas échéant un ou deux atome(s) d'hydrogène étant remplacé(s) par halogène, soit b) alkyle C¿1?-C¿20?, un ou quatre atome(s) d'hydrogène étant remplacé(s) par un radical de formule (II), où R?5¿, R?6¿ et R?7¿ représentent alkyle C¿1?-C¿20?, cycloalkyle C¿3?-C¿8?, aryle C¿5?-C¿20? ou alkylaryle (ces quatre radicaux pouvant être substitués une ou deux fois par halogène et/ou hydroxyle), ainsi que halogène, nitro ou hydrogène, et le cas échéant un ou deux atome(s) d'hydrogène étant remplacé(s) par halogène.

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