Use of supported palladium catalysts in the preparation of...

Details Use of supported palladium catalysts in the preparation of... Use of supported palladium catalysts in the preparation of...

C - Chemistry, Metallurgy

07

C

C07C 31/12 (2006.01) C07C 29/132 (2006.01) C07C 29/88 (2006.01)

Patent

CA 2135560

USE OF SUPPORTED PALLADIUM CATALYSTS IN THE PREPARATION OF TERTIARY BUTYL ALCOHOL FROM TERTIARY BUTYL HYDROPEROXIDE (Docket No. 81,135-F) ABSTRACT OF THE DISCLOSURE A method for preparing tertiary butyl alcohol wherein a solution of a tertiary butyl hydroperoxide feedstock in tertiary butyl alcohol is charged to a hydroperoxide decompo- sition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of palladium and gold supported on alumina, and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol and ditertiary butyl peroxide.

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