Use of tetrafunctional initiators to improve the rubber...

C - Chemistry – Metallurgy – 08 – F

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C08F 279/00 (2006.01)

Patent

CA 2552761

It has been discovered that improved polystyrene products, such as high impact polystyrene (HIPS), may be obtained by polymerizing styrene with a diene polymer in the presence of at least one multifunctional initiator. The presence of the multifunctional initiator tends to cause more branched structures in the polystyrene. Unexpectedly, the ratio of % gel to % rubber (G/R or rubber phase volume) increases as the swell index increases which is the opposite of the conventional trend. Additionally, acceptable G/R values can be achieved at increased polymerization rates with these initiators.

On a découvert, dans la présente invention, que des produits de polystyrène amélioré, tel que le polystyrène antichoc (HIPS), peuvent être obtenus en polymérisant du styrène à l~aide d'un polymère diène en présence d'au moins un initiateur multifonctionnel. La présence de l~initiateur multifonctionnel tend à créer plus de structures ramifiées dans le polystyrène. Le rapport du % de gel au % de caoutchouc (G/C ou volume en phase caoutchouc) augmente, de manière inattendue, quand l'indice de gonflement augmente, ce qui est le contraire de la tendance habituelle. En outre, des valeurs G/C acceptables peuvent être atteintes à des taux de polymérisation supérieurs grâce à ces initiateurs.

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