Vanadium (iv) oxide bis (dialkyldithiocarbamates) and...

C - Chemistry – Metallurgy – 07 – F

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C07F 9/00 (2006.01) C10M 135/18 (2006.01) C10M 135/20 (2006.01) C10M 139/00 (2006.01)

Patent

CA 2079203

Abstract Vanadium(IV) oxide bis(dialkyldithiocarbamates) of the general formula Image I in which R denotes identical or different, branched or straight- chain, saturated or unsaturated alkyl radicals having 1 - 18 carbon atoms or cycloalkyl radicals having 4 - 7 carbon atoms and a process for their preparation, in which process 2 mols of an alkali metal dialkyldithiocarbamate of the general formula Image II in which R and R1 are as defined in claim 1 and Me represents sodium, potassium or ammonium, are reacted with 1 mol of vanadium(IV) oxide sulfate: pentahydrate in methanol or water as solvent. The novel vanadium dithiocarbamates can be used as additives for permanent gear lubrication oils or hydraulic oils.

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