Vapor phase polmerization with temporarily inactive titanium...

C - Chemistry – Metallurgy – 08 – F

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402/381, 402/610

C08F 2/34 (2006.01) B01J 8/10 (2006.01) B01J 8/36 (2006.01) B01J 8/38 (2006.01) B01J 19/18 (2006.01) C08F 4/64 (2006.01) C08F 10/00 (2006.01)

Patent

CA 1103396

ABSTRACT Vapor phase polymerization of an olefin which comprises conveying inactive high yield titanium catalyst component to a vapor phase polymerization reactor with a liquid comprising recycled quench liquid, reactivating said inactive high yield titanium catalyst component inside the reactor with a metal alkyl reducing agent and polymerizing olefin under has phase polymeri- zation conditions with reactivated high yield catalyst to form a resinous polymer of an olefin having a low level of catalyst residues.

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