Very fine-sized aqueous polymeric microemulsions

C - Chemistry – Metallurgy – 08 – F

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9/58, 400/9043

C08F 2/24 (2006.01) C08F 20/00 (2006.01) C08F 220/12 (2006.01) D21H 17/37 (2006.01) D21H 17/39 (2006.01)

Patent

CA 2013318

ABSTRACT Aqueous polymeric microemulsions such as acryl- ic ester copolymers contain very fine particles having a number average particle size of generally 600 Angstroms or less. The glass transition temperature of the parti- cles is low and with respect to acrylic polymers is generally 20°C or lower. The aqueous polymeric micro- emulsion can can be based on polymers such as an acrylic polymer or copolymers thereof, vinylidene chloride poly- mers or copolymers, acrylonitrile-butadiene (nitrile) polymers or copolymers thereof, polyvinyl chloride poly- mers or copolymers, vinyl acetate polymers or copolymers, ethylene copolymers, and the like, as well as blends of the above. The polymeric microemulsions are made by uti- lizing at least one water soluble initiator or a redox initiator system and a low but effective amount of one or more emulsifying agents and adding the monomers thereto on an incremental basis. Acrylic polymeric microemul- sions are desired due to their high heat stability. The fine-size polymeric microemulsions have good film forma- tion, high pigment loading ability, unexpectedly high shear holding time, and the like. They are thus suitable for imparting improved strength to paper and when used with various fillers improve the opacity of the paper.

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