Vinyl chloride polymerisation process

C - Chemistry – Metallurgy – 08 – F

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402/375, 402/545

C08F 2/18 (2006.01) C08F 14/06 (2006.01)

Patent

CA 1220898

ABSTRACT "Vinyl Chloride Polymerisation Process" Process for the polymerisation of vinyl chloride in aqueous suspension or microsuspension using an organo soluble free-radical-yielding initiator wherein the initiator is progressively activated during polymerisation by the pro- gressive reduction of a non-initiator-activating water- soluble metal chelate complex to an initiator-activating form of the complex (which is otherwise substantially stable under the polymerisation conditions) in which the metal is in a lower oxidation state, preferably a one- or two lower oxidation state.

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