Water- and oil-repellent

C - Chemistry – Metallurgy – 09 – K

Patent

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Details

C09K 3/18 (2006.01) C08K 5/205 (2006.01) C08L 33/14 (2006.01) D06M 15/277 (2006.01) C08F 220/10 (2006.01) C08F 220/24 (2006.01)

Patent

CA 2702687

Disclosed is a water-repellent oil-repellent agent obtained by adding a blocked isocyanate into an aqueous dispersion of a fluorine-containing copolymer at a weight ratio of 0.05-3.0 relative to the solid content in the aqueous dispersion. The fluorine-containing copolymer contains, as copolymerization units, (a) a perfluoroalkylalkyl (meth)acrylate represented by the following general formula: C n F2n+1C m H2m OCOCR=CH2 (wherein R represents a hydrogen atom or a methyl group, n represents 4, 5 or 6, and m represents 1, 2, 3 or 4), (b) a benzyl (meth)acrylate, (c) a fluorine-free polymerizable monomerother than benzyl(meth)acrylates and (d) a crosslinkable group-containing polymerizable monomer.

L'invention porte sur un agent hydrophobe et oléophobe obtenu en ajoutant un isocyanate bloqué dans la dispersion aqueuse d'un copolymère contenant du fluor à un rapport en poids de 0,05 à 3,0 par rapport à la teneur en matière solide de la dispersion aqueuse. Le copolymère contenant du fluor contient, comme unités de copolymérisation, (a) un (méth)acrylate de perfluoroalkylalkyle représenté par la formule générale suivante : CnF2n+1CmH2mOCOCR=CH2 (dans laquelle R représente un atome d'hydrogène ou un groupe méthyle, n représente 4, 5 ou 6 et m représente 1, 2, 3 ou 4), (b) un (méth)acrylate de benzyle, (c) un monomère polymérisable exempt de fluor autre que les (méth)acrylates de benzyle et (d) un monomère polymérisable contenant un groupe pouvant être réticulé.

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