Water borne pressure sensitive adhesive compositions derived...

C - Chemistry – Metallurgy – 09 – J

Patent

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C09J 133/06 (2006.01) C08F 218/10 (2006.01) C08F 220/12 (2006.01) C09J 131/02 (2006.01)

Patent

CA 2220206

The present invention is directed to improved aqueous based pressure sensitive adhesive emulsion polymers. Conventional emulsion based pressure sensitive adhesives are comprised of a copolymer comprised of polymerized units of acrylic esters and ethylenically unsaturated monomers, the copolymer having a Tg of from -15 to-70°C. The improvement in the aqueous based, emulsion polymerized pressure sensitive adhesives resides in the incorporation of a vinyl C8-13 ester of a neo-acid into the copolymer present in the pressure sensitive adhesives. Such vinyl ester is formed from a mixture of propylene oligomers and such vinyl ester is represented by thechemical formula: C8-13H17-27C02GH=CH2 N:\RLB\186P5499.apl

La présente invention porte sur des polymères en émulsion améliorés pour adhésif sensible à la pression (autocollant) aqueux. Les adhésifs en émulsion autocollants traditionnels sont constitués d'un copolymère comprenant des unités polymérisées d'esters d'acrylique et de monomères à insaturations éthyléniques, le copolymère ayant une Tg de -15 à -70 degrés C. L'amélioration touchant les adhésifs autocollants polymérisés en émulsion réside dans l'incorporation d'un ester de vinyle en C8-C13 d'un néo-acide dans le copolymère présent dans les adhésifs sensibles à la pression. Cet ester de vinyle est formé à partir d'un mélange d'oligomères de propylène et est représenté par la formule chimique : C8-13H17-27C02GH=CH2 N:\RLB\186P5499.apl

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