Water-dispersible carotenoids, including analogs and...

C - Chemistry – Metallurgy – 07 – C

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C07C 403/24 (2006.01) A61K 31/225 (2006.01) A61K 31/6615 (2006.01) A61K 31/665 (2006.01) A61P 27/02 (2006.01) C07F 9/117 (2006.01) C07F 9/655 (2006.01)

Patent

CA 2611137

A chemical composition; comprising one or more carotenoid analogs or derivatives having a structure (I), (II) and (III) where each R3 is independently hydrogen or methyl, and where each R1 and R2 are independently wherein each R5 is independently hydrogen, -OH, or -OR6, wherein at least one R5 group is -OR6; wherein each R6 is independently: alkyl; aryl; -alkyl- N(R7)2; -aryl-N(R7)2; -alkyl-N+ (R7)3; -aryl-N+(R7)3; -alkyl-CO2R7; -aryl- CO2R7; -alkyl-CO2; -aryl-CO2; -CO2R8; -P(O)(OR8)2; -S(O)(OR8)2; an amino acid; a peptide, a carbohydrate; -C(O)- (CH2)0-CO2R9; a nucleoside residue, or a co- antioxidant; wherein R7 is hydrogen, alkyl, or aryl; wherein R8 is hydrogen, alkyl, aryl, benzyl or a co-antioxidant; wherein R9 is hydrogen; alkyl; aryl; - P(0)(OR8)2; -S(0)(OR8)2; an amino acid; a peptide, a carbohydrate; a nucleoside, or a co-antioxidant; and wherein n is 1 to 9. The compounds are useful for the inhibition and amelioration of diseases resulting in change and/or loss of vision.

L'invention porte sur une composition chimique d'un ou plusieurs analogues ou dérivés de caroténoïdes de formule générale (I) dans laquelle: chaque R3 est indépendamment hydrogène ou méthyle, dans laquelle: chaque R1 et R2 est indépendamment: (formule 2, 3) dans laquelle: chaque R5 est indépendamment hydrogène, -OH, ou -OR6, dans laquelle au moins un groupe R5 est -OR6; dans laquelle: chaque R6 est indépendamment: alkyle; aryle; -alkyle-N(R7)2; -aryle-N(R7)2; -alkyle-N+ (R7)3; -aryle-N+(R7)3; -alkyle-CO2R7; -aryle-CO2R7; -alkyle-CO2; -aryle-CO2; -CO2R8; -P(O)(OR8)2; -S(O)(OR8)2; un acide aminé; un peptide, un carbohydrate; -C(O)- (CH2)0-CO2R9; un résidu nucléoside, ou un co-antioxydant; dans laquelle: R7 est hydrogène, alkyle, ou aryle; dans laquelle: R8 est hydrogène, alkyle, aryle, benzyle ou un co-antioxydant; dans laquelle: R9 est hydrogène; alkyle; aryle; -P(0)(OR8)2; -S(0)(OR8)2; un acide aminé; un peptide, un carbohydrate; un nucléoside, ou un co-antioxydant; et dans laquelle: n est 1 à 9. Lesdits composés s'avèrent utiles pour l'inhibition et l'amélioration de maladies produisant des modifications ou une perte de la vision.

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