Water-swellable crosslinked polymeric microgel particles and...

C - Chemistry – Metallurgy – 08 – F

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402/1, 402/404,

C08F 220/02 (2006.01) C08F 220/04 (2006.01) C09D 125/14 (2006.01)

Patent

CA 1223395

ABSTRACT OF THE DISCLOSURE Disclosed are carboxylic acid containing polymeric microgel particles which are prepared by polymerizing in aqueous emulsion a monomer mixture containing about 10-50% by weight of polymerizable carboxylic acid monomers, up to 5% of a difunc- tional crosslinking monomer and one or more carboxyl-free relatively water insoluble polymerizable vinyl monomers. The resulting microgel particles are water-swellable and may be employed as stabilizers for use in the preparation of aqueous dispersions of film-forming resins containing smaller amounts of organic solvents than conventional aqueous dispersions of this type. Such dispersions are useful as coating compositions, yielding coatings having less water sensitivity and improved adhesion as compared with coatings obtained from conventional aqueous dispersions of film-forming resins.

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