Winning metal from ore

C - Chemistry – Metallurgy – 22 – B

Patent

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53/369, 53/374

C22B 15/00 (2006.01) C01G 3/00 (2006.01) C07F 1/00 (2006.01) C22B 3/26 (2006.01) C22B 3/30 (2006.01)

Patent

CA 1225243

ABSTRACT WINNING METAL FROM ORE Copper is won from chalcopyrite ore (copper/iron sulphide) containing Cu(II) and Fe(III), which respectively prefer square planar and octahedral co-ordination. A vapourised tetradentate (square-planar) Schiff base reagent is passed through a fluidised bed of oxidatively roasted chalcopyrite, and ignores the iron but forms a (volatile) copper complex. This is blown to a decomposition chamber containing a hot probe on which the complex decomposes, leaving the desired copper on the probe and liberating the Schiff base reagent for recycling.

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