Zeolite rho and zk-5 catalysts for conversion of methanol...

C - Chemistry – Metallurgy – 07 – C

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C07C 209/16 (2006.01) B01J 29/70 (2006.01) C07C 211/04 (2006.01)

Patent

CA 1280125

TITLE IMPROVED ZEOLITE RHO AND ZK-5 CATALYSTS FOR CONVERSION OF METHANOL AND AMMONIA TO DIMETHYLAMINE ABSTRACT Improved acidic zeolite rho and ZK-5 catalysts for conversion of methanol and ammonia to dimethylamine are disclosed. The acidic zeolite rho catalyst is prepared by calcining zeolite NH4-rho or H-rho in the presence of steam. The acidic zeolite ZK-5 catalyst is prepared by calcining zeolite NH4-ZK-5 or H-ZK-5 in the presence of steam. An acidic zeolite rho which has been prepared by calcining zeolite NH4-rho in a vertical furnace in the presence of ammonia is disclosed. Processes for producing dimethylamine with the specified catalysts are also disclosed.

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