Tricyclic compounds

C - Chemistry – Metallurgy – 07 – D

Patent

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260/355.5, 260/3

C07D 239/00 (2006.01) C07D 313/14 (2006.01) C07D 337/14 (2006.01)

Patent

CA 1043342

ABSTRACT OF THE DISCLOSURE This invention relates to a process for the manufacture of compounds of the formula Image I wherein X represents an oxygen or sulphur atom, R1 represents a hydrogen atom or a lower alkyl group, R6' represents a halogen atom or a lower alkyl, lower alkoxy, lower alkylthio, lower alkylsulphonyl, di(lower alkyl)sulphamoyl, hydroxy, benzyloxy, trimethylsilyloxy, trifluoromethyl, nitro, amino or di(lower alkyl)amino group, R7' and R8' each individually represent a hydro- gen atom or a substituent denoted by R6' and Y represents lower alkylsulfonyl- oxy, lower arylsulfonyloxy, chlorine or bromine, which comprises reacting a compound of the formula Image II wherein X, R1 and R6' - R8' have the above meanings, with a lower alkyl- or lower arylsubstituted sulfonic acid halide or thionyl chloride or bromide The dibenzo[b,f]thiepin and dibenz[b,f]oxepin derivatives of formula I are useful as starting materials for the manufacture of dibenzo[b,f]thiepin and dibonz[b,f]oxopin derivatives which form the subject matter of our copending Canadian Application for Letters Patent No 201,871 filed June 6, 1974.

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