Chromogenic propenylenesulfone compounds

C - Chemistry – Metallurgy – 09 – B

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42/2, 260/306, 2

C09B 23/06 (2006.01) B41M 5/136 (2006.01) B41M 5/323 (2006.01) C07D 209/10 (2006.01) C07D 209/80 (2006.01) C07D 209/86 (2006.01) C07D 295/096 (2006.01) G03G 5/09 (2006.01)

Patent

CA 1134835

Abstract of the Disclosure Chromogenic compounds of the formula Image (1A) or Image (1B) wherein each of Y1 and Y2 independently represents an amino- substituted phenyl radical of the formula Image (1a) a 3-indolyl radical of the formula Image (1b) or - 2 - a 3-carbazolyl radical of the formula Image (1c) and Q represents alkyl of 1 to 12 carbon atoms or unsubstituted or substituted aryl or aralkyl, whilst each of X1 and X2 independently represents hydrogen, alkyl containing not more than 12 carbon atoms which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy. or represents cycloalkyl, phenyl, benzyl, or phenyl or benzyl which is substituted by halogen, lower alkyl or lower alkoxy, or X1 and X2 together with the nitrogen atom to which they are attached represent a 5- or 6-membered heterocyclic radical, X3 represents hydrogen, halogen, nitro, lower alkyl or lower alkoxy, each of R and Z1 independently represents hydrogen, alkyl containing not more than 12 carbon atoms which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, or represents alkenyl containing not more than 12 carbon atoms, acyl of 1 to 12 carbon atoms, phenyl, benzyl, or phenyl or benzyl which is substituted by halogen, lower alkyl, lower alkoxy or nitro, and Z2 represents hydrogen. lower alkyl or phenyl, and the rings A, B and D, each independently of the other, can be unsubstituted or sub- stituted by cyano, nitro, halogen, lower alkyl, lower alkoxy or lower alkoxycarbonyl, and the ring D can also contain an unsubstituted or substituted phenyl radical or a fused benzene ring. These compounds are particularly suitable for use as colour formers in pressure-sensitive or heat-sensitive recording materials.

336009

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