Process for the production of oxygenated hydrocarbons from...

C - Chemistry – Metallurgy – 07 – C

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260/571, 260/638

C07C 31/08 (2006.01) B01J 23/46 (2006.01) B01J 31/00 (2006.01) C07C 29/151 (2006.01) C07C 29/158 (2006.01) C07C 29/32 (2006.01) C07C 45/49 (2006.01) C07C 47/06 (2006.01) C07C 51/10 (2006.01) C07C 51/12 (2006.01) C07C 69/14 (2006.01)

Patent

CA 1151670

ABSTRACT OF THE DISCLOSURE Oxygenated hydrocarbons are produced by reacting in a liquid medium carbon monoxide and hydrogen in the presence of a particulate catalyst comprising a supported rhodium component at an elevated temperature, typically in the range 150 to 300°C and an elevated pressure, typically greater than 50 bars. Suitable liquid media include water, an alcohol, a carboxylic acid, an ester, a ketone, an ether or an aromatic hydrocarbon. The rhodium catalyst may be supported on silica and is desirably combined with other metals.

369020

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