Polyester polyols and their use as polyol component in...

C - Chemistry – Metallurgy – 07 – C

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117/195, 402/203

C07C 69/80 (2006.01) C08G 18/42 (2006.01) C08G 63/20 (2006.01)

Patent

CA 1252797

NEW POLYESTER POLYOLS AND THEIR USE AS POLYOL COMPONENT IN TWO-COMPONENT POLYURETHANE LACQUERS ABSTRACT OF THE DISCLOSURE The present invention relates to polyester polyols having a hydroxyl number of about 80 to 250, containing reaction products of a) 54 to 58 mol % of a polyol component and b) 46 to 42 mol % of a dicarboxylic acid component, characterized in that a) the polyol component contains (i) about 70 to 90 mol % of hexane-1,6-diol and (ii) about 10 to 30 mol % of at least one higher valent alcohol selected from trimethylolpropane, glycerol, pentaerythritol and mixtures of these polyols, and b) the dicarboxylic acid component contains (iii) about 50 to 80 mol % of isophthalic acid, (iv) about 20 to 30 mol % of at least one dicarboxylic acid of the formula HOOC-(CH2)n-COOH (n = an integer from 2-8) and (v) 0 to about 20 mol % of at least one dicarboxylic acid or at least one dicarboxylic acid anhydride selected from terephthalic acid, phthalic acid, phthalic acid anhydride, tetrahydrophthalic acid, tetrahydrophthalic acid anhydride, hexahydrophthalic acid and hexahydrophthalic acid anhydride. The invention also relates to the use of these polyester polyols as the binder component for two-component polyurethane lacquers containing lacquer polyisocyanates for the production of lacquer coatings on molded plastics parts.

482089

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