Isobutene by dehydroisomerisation of normal butane

C - Chemistry – Metallurgy – 07 – C

Patent

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260/648, 260/705

C07C 11/09 (2006.01) C07C 5/373 (2006.01) C07C 43/04 (2006.01)

Patent

CA 1170279

ABSTRACT OF THE DISCLOSURE This invention relates to a method of dehydroisomerising n-butane by contacting at elevated temperatures a feedstock containing n-butanes with a catalyst composition containing a gallium compound on a support. The process affords a valuable method of producing iso-butane which is a basic chemical feedstock for a number of products including polyisobutenes, methacrolein and methyl tertiary butyl ether, to name a few. The last named compound can be prepared by reacting isobutene. with methanol and is a convenient means of separating iso-butene from the products of the dehydroisomerisation stage.

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