Process for the preparation of conductive polymers or...

C - Chemistry – Metallurgy – 08 – F

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400/2008, 402/9

C08F 8/42 (2006.01) C08C 19/00 (2006.01) C08C 19/25 (2006.01) H01B 1/12 (2006.01)

Patent

CA 1272833

Abstract The invention relates to a process for the pre- paration of conductive polymers or prepolymers and to con- ductive polymers or prepolymers. The process of the invention consists of reacting a polymer containing ethylenic unsaturations such as a hydroxytelechelic polybutadiene with a silane compound of formula Image in which R1 denotes a hydrocarbon group containing at least one heteroatom bearing mobile electrons such as the oxygen of an ether group and R2 and R3 denote a substituted or unsubsti- tuted organic residue or a group R1. The polymer obtained is precipitated by the ad- dition of a compound which is not a solvent for the polymer and is separated from the reaction medium. The polymers obtained have an electrical conduc- tivity which is multiplied by a factor of 105 relative to the unmodified polymer. The present invention applies in particular in the field of the polymer industry.

505858

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