Method of preparing flame retardant oligomeric phosphate esters

C - Chemistry – Metallurgy – 07 – F

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260/461.5

C07F 9/141 (2006.01) C07F 9/09 (2006.01) C08G 79/04 (2006.01) C08J 9/00 (2006.01)

Patent

CA 1127176

METHOD OF PREPARING FLAME RETARDANT OLIGOMERIC PHOSPHATE ESTERS ABSTRACT OF THE DISCLOSURE Flame retardant oligomeric phosphate ester compositions having the structural formula: Image are prepared, wherein R is C1-C10 alkyl or haloalkyl, R1 and R2 can be the same or different and are hydrogen, C1-C10 alkyl or haloalkyl and n is an integer from about 2 to about 10. The method of preparing the compositions com- prises reacting P2O5 with a trialkyl or tris(haloalkyl) phosphate in the presence of about 0.01% to about 5% of a phosphite at a temperature from about 0°-200°C. A polyphosphate ester having P-O-P bonds is formed which is then reacted with an epoxide to yield the oligomeric phosphate ester flame retardant composi- tions. Alternatively, a method of preparing similar compositions comprises reacting P2O5 with a trialkyl or tris(haloalkyl)phosphite at a temperature from about 0°C. to about 200°C. A mixed polyphosphate- polyphosphite ester having P-O-P bonds is formed C-5128/5227 which is then oxidized to yield a polyphosphate having P-O-P bonds; which is the reacted with an epoxide to yield the oligomeric phosphate ester flame retardant compositions. C-512B/5227

322892

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