Process for the preparation of thiuram disulfides

C - Chemistry – Metallurgy – 08 – L

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260/306.3, 260/5

C08L 21/00 (2006.01) A01N 47/26 (2006.01) C07D 401/12 (2006.01) C08J 3/24 (2006.01) C08K 5/40 (2006.01)

Patent

CA 1183160

ABSTRACT OF THE DISCLOSURE A process for the preparation of thiuram disulfides substituted with aliphatic cycloaliphatic, araliphatic, or aromatic hydrocarbon radicals, said process comprising react- ing a suitably substituted secondary amine having a PKa 28 with carbon disulfide in a solvent and in the presence of oxygen or oxygen-containing gas, a solvent, and a metalli- ferous catalyst, at a temperature of between 0°C and 200°C.

396373

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