Process for the preparation of dialkyl vinylphosphonates

C - Chemistry – Metallurgy – 07 – F

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260/458.4

C07F 9/40 (2006.01)

Patent

CA 1297494

HOE 87/F 065 Abstract: A process for the production of dialkyl esterr of vinyl phosphonic acid which comprises subjecting dialkyl esters of 2-acetoxyethane phosphonic acid to cleavage by contacting with a liquid catalytically acting medium at a temperature in the range from 150 to 270°C and under a pressure such that the partial pressures of the total of the components of the reac- tion system is in the range from 1 to 500 mbar, and drawing off the resultlng dialkyl esters of vinyl phosphonic acid and other volatile reaction products.

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