Semi-refined mixed dicarboxylic acids

C - Chemistry – Metallurgy – 07 – C

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260/524.4, 260/5

C07C 55/14 (2006.01) C07C 51/42 (2006.01)

Patent

CA 1208239

ABSTRACT OF THE DISCLOSURE A process is disclosed for recovering a semi-re- fined mixture of adipic, glutaric and succinic acids from an aqueous mixture comprising the acids together with catalyst res- idues and impurities. The process comprises the steps of: (a)adding to the aqueous mixture a reducing agent consisting essentially of hypophosphorous acid or sodium hypophosphite, (b)concentrating the resulting aqueous mixture to remove water to produce a substantially dehydrated mixture; and (c)feeding the substantially dehydrated mixture to an evaporator and evapo- rating therefrom a mixture of adipic, glutaric and succinic acids. The mixture of adipic, glutaric and succinic acids may then be condensed as a molten material and fed to a flaker to produce a product in flake form.

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