Prostacyclin derivatives, process for the preparation...

C - Chemistry – Metallurgy – 07 – D

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C07D 307/935 (2006.01) C07C 45/41 (2006.01) C07D 307/937 (2006.01) C07D 317/06 (2006.01) C07D 317/30 (2006.01) C07D 319/06 (2006.01) C07D 407/00 (2006.01) C07D 407/06 (2006.01) C07F 7/18 (2006.01)

Patent

CA 1252088

ABSTRACT OF THE DISCLOSURE 5-Cyanoprostacyclins of Formula I I, Image wherein A is a -CH2-CH2-, trans-CH=CH-, or -C=C-group, W is a free or functionally modified hydroxymethylene group or a free or functionally modified Image group wherein the OH-group can be in the .alpha.- or .beta.-posi- tion, D and E together form a direct bond or D is the group , a straight-chain, sat- Image urated alkylene group of 1-5 carbon atoms, a branched, saturated or a straight-chain, unsaturated alkylene group of 2-5 carbon atoms, any of which can optionally be sub- stituted by fluorine atoms, n is the number 1, 2, or 3, E is oxygen, sulfur, a -C=C-bond, a direct bond, or a -CR4=CR5-group wherein R4 and R5 are different and can be a hydrogen atom or an alkyl group of 1-3 carbon atoms, R2 is an alkyl, cycloalkyl, optionally substituted aryl, or heterocyclic group, R1 is a free or functionally modified hydroxy group, and R3 is an acetal residue Image wherein R6, R7, R8, R9, R10 and R11 can be identical or different and each is a hydrogen atom or a straight-chain or branched alkyl group of 1-5 carbon atoms, or an unsubstituted phenyl residue, have valuable pharmacological properties.

457210

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