Catalysts for silylation

Details Catalysts for silylation Catalysts for silylation

C - Chemistry, Metallurgy

07

F

260/100, 260/308

C07F 7/08 (2006.01) C07D 499/00 (2006.01) C07F 7/10 (2006.01) C07F 7/18 (2006.01) C07F 9/24 (2006.01) C07H 23/00 (2006.01) C07J 51/00 (2006.01)

Patent

CA 1184556

ABSTRACT OF THE DISCLOSURE Improved process for the silylation of organic com- pounds with 1,1,1-trimethyl-N-(trimethylsilyl)silanamine by means of catalysis with certain nitrogen containing organic compounds. The organic compounds which may be silylated by the improved process are carrying one or more -OH, NH or SH groups, for example alcohols, phenols, carboxylic acids, amines, amides, aminoacids and thiols. The nitrogen containing cata- lysts are compounds with the general formula X-NH-Y wherein X represents a hydrogen atom, a trialkylsilyl group or an electron-withdrawing group and Y represents an electron- withdrawing group.

381119

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