Process for preparing polyarylates

C - Chemistry – Metallurgy – 08 – G

Patent

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402/202, 400/504

C08G 63/19 (2006.01) C08G 63/81 (2006.01) C08L 67/03 (2006.01)

Patent

CA 1173999

IMPROVED PROCESS FOR PREPARING POLYARYLATES ABSTRACT OF THE INVENTION Described herein is an improved process for preparing a polyarylate having a reduced viscosity of from about 0.5 to greater than 1.0 dl/gm which process comprises the following steps: a) reacting an acid anhydride derived from an acid containing from 2 to 8 carbon atoms with at least one dihydric phenol to form the corresponding diester; and (b) reacting said diester with at least one aromatic dicarboxylic acid at a temperature sufficient to form the polyarylate. wherein the improvement comprises removing residual acid anhydride, after formation of the dihydric phenol diester. so that its concentration is less than about 1500 parts per million. The novel polyarylates produced by the improved process of this invention are melt stable and low in color. S P E C I F I C A T I 0 N D-12,857

383868

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