Manufacturing of high molecular weight polyester

C - Chemistry – Metallurgy – 08 – G

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C08G 63/18 (2006.01) C08G 63/183 (2006.01) C08G 63/80 (2006.01) C08K 3/00 (2006.01) C08K 5/098 (2006.01)

Patent

CA 1250075

Abstract of the Disclosure A polybutylene terephthalate is manufactured by the steps of polycondensating in the liquid phase terephthalic acid or a lower alcohol ester thereof as the acid component and 1,4-butanediol as the diol component to obtain a prepolymer of polybutylene terephthalate, solidifying the prepolymer and further polymerizing the prepolymer in the solid phase to obtain a polybutyrene terephthalate of a higher polymerization degree, 0.001 to 5 percent by weight, based on the prepolymer, of a nucleator being added to the polymerization mixture at any time during a period of from the monomer-mixing stage before the starting of the solid phase polymerization, the solid phase polymerization being conducted in the presence of the nucleator uniformly dispersed in the polymerization mixture. The solid polymerization can be treated subsequently to the liquid polymerization and can proceed in a short time.

498411

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