Process for the preparation of very pure partially...

C - Chemistry – Metallurgy – 07 – C

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260/658.2

C07C 19/00 (2006.01) B01J 27/06 (2006.01) C07C 17/087 (2006.01)

Patent

CA 1196345

Abstract: Process for the preparation of very pure partially fluorinated ethanes The reaction of fluorine-containing ethylenes of the formula CF2=CXY, in which X denotes H or F and Y denotes H, F, C1, Br or iodine, with hydrogen fluoride to form fluorine-containing ethanes of the formula CF3-CHXY is carried out, according to the invention, at temperatures of 20 - 200°C and in the presence of a chromium oxyfluoride catalyst which has been treated with hydrogen fluoride. Only a small amount of by- products is formed in this process.

372965

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