C - Chemistry – Metallurgy – 08 – L
Patent
C - Chemistry, Metallurgy
08
L
400/3070
C08L 75/04 (2006.01) C08G 18/66 (2006.01) C08G 18/76 (2006.01) C08L 75/08 (2006.01)
Patent
CA 1231488
A PROCESS FOR THE PRODUCTION OF THERMOPLASTIC POLYURETHANE ELASTOMERS ABSTRACT OF THE DISCLOSURE Thermoplastic polyurethane elastomers which are flexible at low temperatures, have high mechanical strength, a density of from 1.10 to 1.17 Mg/m3 and a Shore-D hardness of from 55 to 80 are produced by reacting: a) 4,4'-diisocyanatodiphenylmethane or an isomer mixture thereof with b) a polytetramethylene ether diol having a molecular weight of from 800 to 3,000 in the presence of c) a mixture of diol chain extenders, d) a graft rubber polymer and optionally e) an antioxidant and/or UV-absorber/light stabilizer. The molar ratio of a) to b) is between 6:1 and 50:1. The mixture of diol chain extenders is made up of (1) 1,4-butane diol or 1,6-hexane diol and (2) a diol different from (1) having a molecular weight of from 62 to 399. The molar ratio of diol (1) to diol (2) is from 97:3 to 72:28. These elastomers are particularly useful in the production of automobile and ski boot components.
473527
Goyert Wilhelm
Hoppe Hans-Georg
Wagner Hans
Winkler Jurgen
Aktiengesellschaft Bayer
Marcoux & Sher Swabey Mitchell Houle
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