Hydrocarbon oxidations catalyzed by nitride-activated metal...

Details Hydrocarbon oxidations catalyzed by nitride-activated metal... Hydrocarbon oxidations catalyzed by nitride-activated metal...

C - Chemistry, Metallurgy

07

C

260/494.3, 260/5

C07C 27/12 (2006.01) B01J 27/24 (2006.01) B01J 31/18 (2006.01) C07C 29/50 (2006.01) C07C 45/33 (2006.01) C07C 45/34 (2006.01) C07C 45/35 (2006.01) C07C 45/36 (2006.01) C07C 49/08 (2006.01) C07C 49/403 (2006.01)

Patent

CA 1302433

ABSTRACT Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O2 to form such products as alcohols, ketones, and the like in high yields when there is employed as the catalyst a highly active nitride-activated metal coordination complex having the structure Image where M is a transition metal; " Image " is a ligand; and X is a nitride. Certain dimeric forms of the above catalyst are also employed herein. It has also been discovered that Group IV through VIII transition metal nitrides are also highly effective oxidation catalysts for lower molecular weight hydrocarbons such as alkanes. LD/E47

553416

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