Functional electrode

C - Chemistry – Metallurgy – 25 – D

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Details

204/195, 204/24.

C25D 11/32 (2006.01) C09K 19/04 (2006.01) G01N 27/30 (2006.01)

Patent

CA 1211408

ABSTRACT A method of producing, a functional electrode comprising: providing an aqueous solution containing MI ions, M(III) ions and [M'(III)(CN)6]3- ions; with the proviso that said solution does not contain both Fe(III) ions and [Fe(II)(CN)6]3- ions; and electrodepositing a compound of the formula MIM(III)[M'(II)(CN)6] or M(III)4[M'(II)(CN)6]3 on a conductor from said aqueous solution, wherein M(III) and M'(III) are each selected from Fe(III), Ru(III) or Os(III), M'(II) is Fe(II), Ru(II) or Os(II) and MI is an alkali metal cation, with the proviso that said compound does not contain both Fe(III) and Fe(II). The novel electrode is functional as a catalyst electrode effective to catalyze the evolution of oxygen and chlorine gases during electrolytic processes and as electrochromic display element.

418904

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