Production of 1,1,1,3-tetrachloropropane

Details Production of 1,1,1,3-tetrachloropropane Production of 1,1,1,3-tetrachloropropane

C - Chemistry, Metallurgy

07

C

260/663.1

C07C 17/28 (1985.01) C07C 19/02 (1985.01)

Patent

CA 1273645

ABSTRACT In the reaction of carbon tetrachloride with ethylene in the presence of a catalyst comprising a phosphite ester and an iron- containing material to produce 1,1,1,3 tetrachloropropane, the improvement in the yield of the process which is achieved by employing powdered iron as the iron-containing material. Thereby the carbon tetrachloride is converted with increased yields and with high selectivity to the desired product. The reaction also proceeds well even under milder conditions than with the catalysts of the prior art.

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