Urethanes made from aliphatic fluorinated alcohols,...

C - Chemistry – Metallurgy – 07 – C

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260/468, 8/93.23

C07C 271/28 (2006.01) C07C 275/14 (2006.01) C07C 275/62 (2006.01) C08G 18/28 (2006.01) C08G 18/32 (2006.01) C14C 11/00 (2006.01) D06M 13/425 (2006.01) D06M 15/576 (2006.01)

Patent

CA 1305174

23221-4576 Abstract of the disclosure Urethanes made from aliphatic fluorinated alcohols, iso- cyanates and substituted aromatic compounds, a process for their preparation, and their use. Novel urethanes of the general formula Image (1), in which Rf denotes, for example, a C4-C20 perfluoroalkyl, R1 is H or C1-C4 alkyl, X is an integer from 1 to 4, Y is an integer from 0 to 10, m and n are integers from 1 to 2, the sum m + n being at most 3, and A is, for example, a phenylene or toluylene group are disclosed. The novel urethanes are synthesized from an aliphatic fluorinated alcohol, an isocyanate and a specific substituted phenol or aniline compound. They are prepared by reacting an aliphatic fluorinated alcohol with a di - or triisocyanate to form a fluorinated alcohol/isocyanate adduct and reacting this adduct with a certain substituted phenol or aniline to form the urethanes intended. The novel urethanes are preferably used for oleophobic and hydrophobic finishing of textiles and leather.

587105

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