Highly siliceous porous crystalline material, method of...

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B01J 29/04 (2006.01) B01J 29/70 (2006.01) B01J 29/80 (2006.01) B01J 29/88 (2006.01) B01J 29/89 (2006.01)

Patent

CA 1182796

ZEOLITE,METHOD OF PREPARING SAME AND CATALYTIC CONVERSION THEREWITH Abstract A new metal-containing highly siliceous porous crystalline material related to the structure of zeolite beta, a method of making same and the use thereof in catalytic conversion of organic compounds. The anhydrous form of the new metal-containing crystal has a calculated composition, expressed in terms of moles of anhydrous oxides per 100 moles of silica, as follows: (W)Q2O ? (X)M2/nO ? (Y)L2O3 ? 100 SiO2 wherein Q2O is the oxide form of an organic compound containing an element of Group 5-B of the Periodic Table, said organic compound having at least one alkyl or aryl group at least one of which is an ethyl, M is an alkali metal, W = <5, X = <2, Y = <4, and L = Al, Cr, Fe, or La and mixtures thereof, provided that at least one of Cr, Fe and La is present and Y is > zero. The new crystal is prepared from a reaction mixture comprising a source of silica, chromium and/for iron compounds and/or lanthanum oxide, a source of organic compounds of Group 5-B, having at least one ethyl group, and water, in the absence of any added alumina in the recipe.

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