Star/comb-branched polyamides and star/comb-branched...

C - Chemistry – Metallurgy – 08 – G

Patent

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402/2, 400/2001

C08G 75/00 (2006.01) C08G 69/00 (2006.01) C08G 73/02 (2006.01)

Patent

CA 1265641

ABSTRACT A star-branched polyamide having at least 3 branches emanating from the residue of a core compound pending from a substantially linear polymer backbone wherein each branch has a plurality of amide moieties in which each such amide moiety has its amide nitrogen in the chain of the branch and each such amide nitrogen bears a pendant carbonyl moiety, said amide moieties being hydrolyzable to form amine moieties without cleaving the chain of the branch. Star-branched polyamides having good resistance to degradation upon exposure to shear are prepared by reacting polyvalent core compounds such has tribromoneopentyl alcohol with an oxazoline such as 2-ethyl-2-oxazoline to provide the desired polyamide. The polyamides are readily hydrolyzed with acid such as hydrochloric acid to form/star/comb-branched polyamines. The polyamides and the polyamines are useful as viscosity enhancing agents in such applications as paints, mobility control agents and hydraulic fluids. 31,963-F

494117

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