Method of selective reduction of halodisilanes with alkyltin...

C - Chemistry – Metallurgy – 01 – B

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C01B 33/107 (2006.01)

Patent

CA 1310469

METHOD OF SELECTIVE REDUCTION OF HALODISILANES WITH ALKYLTIN HYDRIDES ABSTRACT The invention relates to the selective and sequential reduction of halodisilanes by reacting these compounds at room temperature or below with trialkyltin hydrides or dialkyltin dihydrides without the use of free radical intermediates. The alkyltin hydrides selectively and sequentially reduce the Si-Cl, Si-Br or Si-I bonds while leaving intact the Si-Si and Si-F bonds present.

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