Phosphate ester synthesis without phosphorylation catalyst

C - Chemistry – Metallurgy – 07 – F

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260/461

C07F 9/12 (2006.01)

Patent

CA 1221981

PHOSPHATE ESTER SYNTHESIS WITEIOUT PHOSPHORYLATION CATALYST ABSTRACT OF THE DISCLOSURE: Triarylphosphates are prepared by phosphorylation of alkylphenols without use of phosphorylation catalyst. An improved phosphorylation step includes preheating alkylphenol feedstock to 150°C. and completing reaction at 215°C. or above in the presence of a stoichiometric excess of alkylphenol. The absence of phosphorylation catalyst simplifies distillative purification of re- action product by eliminating the need to withdraw puri- fied product as distillate. * * * * * *

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