Hard compositions and methods of preparation

C - Chemistry – Metallurgy – 22 – C

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75/166, 75/1.2

C22C 1/05 (2006.01) C22C 32/00 (2006.01)

Patent

CA 1180576

ABSTRACT OF THE DISCLOSURE Novel very hard compositions of matter are prepared by using in all embodiments only a minor amount of a particu- lar carbide (or materials which can form the carbide in situ when subjected to heat and pressure); and no stra- tegic cobalt is needed. Under a particular range of con- ditions, densified compositions of matter of the invention are prepared having hardnesses on the Rockwell A test sub- stantially equal to the hardness of pure tungsten carbide and to two of the hardest commercial cobalt-bonded tung- sten carbides. Alternately, other compositions of the invention which have slightly lower hardnesses than those described above in one embodiment also possess the advan- tage of requiring no tungsten and in another embodiment possess the advantage of having a good fracture toughness value. Photomicrographs show that the shapes of the grains of the alloy mixture with which the minor amount of carbide (or carbide-formers) is mixed are radically alter- ed from large, rounded to small, very angular by the addi- tion of the carbide. Superiority of one of these hard compositions of matter over cobalt-bonded tungsten carbide for ultra-high pressure anvil applications was demonstrated.

395081

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