B - Operations – Transporting – 01 – J
Patent
B - Operations, Transporting
01
J
260/601
B01J 23/56 (2006.01) B01J 23/54 (2006.01)
Patent
CA 1211127
A B S T R A C T "PROCESS FOR THE SELECTIVE PREPARATION OF ANILINES SUBSTITUTED IN THE META-POSITION(S) BY CHLORINE" A process for the preparation of anilines substituted in the meta-position(s) by chlorine by the catalytic hydrogenation, in the liquid phase, under the action of heat and under pressure, in the presence of a noble metal from Group VIII of the Periodic Table of the Elements of an aniline or nitrobenzene derivative of the general formula: Image (I) (wherein Y represents the hydrogen atom or the oxygen atom, X' and X" each represent a chlorine or hydrogen atom, or an optionally substituted alkyl, aryl, aralkyl, alkoxy, aryloxy or aralkoxy radical, at least one of X' and X" representing a chlorine atom, and R', R" and R"' each represent a chlorine or hydrogen atom, or an optionally substituted alkyl, aryl, aralkyl, alkoxy or aryloxy radical, at least one of the three symbols R', R" and R"' representing a chlorine atom) characterised in that the reaction is carried out in the presence of a co-catalyst based on at least one heavy metal belonyiny to one of the columns Ib to Via of the Periodic Table. The meta-chloroaniline products are useful in the manufacture inter aliah of plant-protection products.
382849
Cordier Georges
Fouilloux Pierre
Macrae & Co.
Rhone-Poulenc Agrochimie
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