Process for the dimerization of olefins

C - Chemistry – Metallurgy – 07 – C

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252/53.A, 260/70

C07C 2/32 (2006.01) B01J 31/18 (2006.01) B01J 31/26 (2006.01)

Patent

CA 1310004

T 130 A B S T R A C T PROCESS FOR THE DIMERIZATION OF OLEFINS A process for the dimerization of alpha-alkenes having 2 to 12 C atoms in the presence of an alkanediol solvent and of a novel catalytic system formed by combining:- a) a palladium(II) compound, b) a chelate ligand comprising a compound containing at least two N coordinating atoms which are connected through a chain comprising two C atoms, > 2.0 mol chelate ligand per gram-atom Pd being used, c) a protonic acid, except hydrohalogenic acids, and d) a salt of Cu, Fe, Zn, Sn, Mn, V, Al or a Group 6b metal, except a halide. EKRH04

558298

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