Preparation of aldols

C - Chemistry – Metallurgy – 07 – C

Patent

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260/570.7

C07C 45/75 (2006.01) C07C 47/198 (2006.01) C07C 51/27 (2006.01) C07H 15/04 (2006.01)

Patent

CA 1250593

Abstract of the Disclosure: Novel ether-aldols of the general formula (I) Image where R1 and R2 are each alkyl, can be prepared by re- acting a 2-alkylacrolein (H2O = CHR2-CHO), an alcohol (R1OH) and formaldehyde, preferably aqueous formaldehyde, in the presence of a tertiary amine. These ether-aldols are useful intermediates particularly in the production of ethermalonic acids, important as crop protection agents.

456499

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