Process for the manufacture of carbon disulphide and use of...

C - Chemistry – Metallurgy – 01 – B

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C01B 31/26 (2006.01) B01J 21/04 (2006.01) B01J 21/06 (2006.01) B01J 21/12 (2006.01) C01B 31/02 (2006.01) C01B 31/18 (2006.01) C01B 31/20 (2006.01)

Patent

CA 2656776

The invention provides a process for the manufacture of carbon disulphide by reacting carbon monoxide with elemental sulphur to form carbonyl sulphide and disproportionating the carbonyl sulphide formed into carbon disulphide and carbon dioxide, the process comprising contacting a gaseous stream comprising carbon monoxide with a liquid elemental sulphur phase containing a solid catalyst at a temperature in the range of from 250 to 700 °C to obtain a gaseous phase comprising carbonyl sulphide, carbon disulphide and carbon dioxide. The invention further provides the use of a liquid stream comprising carbon disulphide, carbonyl sulphide and carbon dioxide obtainable by such process for enhanced oil recovery.

L'invention concerne un procédé pour la fabrication de disulfure de carbone par réaction de monoxyde de carbone avec du soufre élémentaire afin de former du sulfure de carbonyle et par disproportionation du sulfure de carbonyle formé en disulfure de carbone et dioxyde de carbone, le procédé comprenant la mise en contact d'un courant gazeux comprenant du monoxyde de carbone avec une phase de soufre élémentaire liquide contenant un catalyseur solide à une température se situant dans la plage de 250 à 750 °C afin d'obtenir une phase gazeuse comprenant du sulfure de carbonyle, du disulfure de carbone et du dioxyde de carbone. L'invention concerne également l'utilisation d'un courant liquide comprenant du disulfure de carbone, du sulfure de carbonyle et du dioxyde de carbone pouvant être obtenu par un tel procédé pour une récupération améliorée de l'huile.

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