Integrated hfc trans-1234ze manufacture process

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 17/25 (2006.01) C07C 17/358 (2006.01) C07C 17/383 (2006.01) C07C 21/18 (2006.01)

Patent

CA 2598382

An integrated process for the manufacture of HFO trans-1,3,3,3--tetrafluoropropene (HFO trans-1234ze) by first catalytically dehydrofluorinating 1.1,1,3,3-pentafluoropropane to thereby produce a mixture of cis-1,3.3,3-tetrafluoropropene, trans-1,3,3,3-tetrafluoropropene and hydrogen fluoride. Then optionally recovering hydrogen fluoride, catalytically isomerizing cis-1234ze into trans-1234ze, and recovering trans-1,3,3,3--tetrafluoropropene.

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