Process for the synthesis of...

C - Chemistry – Metallurgy – 07 – D

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C07D 401/14 (2006.01) C07D 405/14 (2006.01) C07D 409/14 (2006.01)

Patent

CA 2041031

31,251 IMPROVED PROCESS FOR THE SYNTHESIS OF N-[3-1H-IMIDAZOL-1-YL)PHENYL-4- (SUBSTITUTED)-2-PYRIMIDINAMINES ABSTRACT The invention provides a novel process for producing N-[3-(1H-imidazol-1-yl-4-(substituted-2- pyrimidinamine compounds in which the substituent is a 2-pyridinyl, 3-pyrindinyl, 4-pyridinyl, 2-furanyl or 2-thienyl group. The process includes the steps of (1) reacting a 3-(1H-imidazol-1-yl)benzamine with cyanamide and a halogen acid while controlling the pH of the reaction between pH about 2 to about 3.5 and recovering a [3-(1H-imidazol-1-yl)phenyl] guanidine dihydrohalide and (2) reacting the [3-(1H-imidazol-1-yl)phenyl] quanidine dihydrohalide so recovered with an appropriately substituted 3-dimethylamino-1-(substitut- ed)-2-propen-1-one and a base at a pH of from about 10.5 to about 11.5 and recovering the N-[3-(1H-imidaz- ol-1-yl)phenyl-4-(substituted)-2-pyrimidamine compound so produced. The novel process provides improved yield and purity by adhering to the stated crucial pH ranges.

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