Living radical polymerization of vinyl monomers

C - Chemistry – Metallurgy – 08 – F

Patent

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Details

C08F 4/72 (2006.01) C08F 2/38 (2006.01) C08F 4/44 (2006.01) C08F 4/60 (2006.01) C08F 10/00 (2006.01) C08F 20/06 (2006.01) C08F 20/10 (2006.01) C08F 297/06 (2006.01)

Patent

CA 2183240

This invention relates generally to a living free radical polymerization of alkene monomers through use of persistent metal centered radicals to attain control of the propagation and termination steps in radical polymerization. This process is useful for controlling the molecular weight of homopolymers or copolymers and for forming block copolymers.

La présente invention concerne généralement la polymérisation vivante par radicaux libres de monomères d'alcène par utilisation de radicaux persistants à centres métalliques pour réguler les étapes de propagation et de terminaison dans la polymérisation par radicaux. Ce procédé permet d'obtenir le poids moléculaire voulu des homopolymères ou des copolymères et de former des copolymères séquencés.

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