Process for the preparation of aromatic beta-diketones

C - Chemistry – Metallurgy – 07 – C

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C07C 45/72 (2006.01) C07C 45/45 (2006.01) C07C 49/76 (2006.01) C07C 49/782 (2006.01) C07C 205/45 (2006.01) C07C 323/22 (2006.01) C07D 317/46 (2006.01) C07D 317/54 (2006.01)

Patent

CA 2039375

A process for the preparation of aromatic beta-diketones having the structural formula (see formula I) by the reaction of an acetophenone and a molar excess of an alphatic ester or an ester of benzoic acid in the presence of sodium alkoxide condensation agent in an aromatic hydrocarbon solvent. Also disclosed is a method of recycling the solvent and excess ester reactant after separation of the aromatic beta-diketone product.

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