Polymeric transition metal complexes and uses thereof

C - Chemistry – Metallurgy – 07 – F

Patent

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C07F 15/00 (2006.01) C07F 9/00 (2006.01) C07F 15/02 (2006.01) C07F 15/06 (2006.01) C08F 8/44 (2006.01) C12Q 1/00 (2006.01) G01N 27/49 (2006.01)

Patent

CA 2391423

Novel polymeric transition metal complexes of iron, cobalt, ruthenium, osmium, and vanadium are described. The polymeric transition metal complexes can be electron transfer mediators in enzyme-based electrochemical sensors. In such instances, transition metal complexes accept electrons from, or transfer electrons to, enzymes at a high rate and also exchange electrons rapidly with the sensor.

L'invention concerne de nouveaux complexes polymères de métaux de transition, à base de fer, de cobalt, de ruthénium, d'osmium, et de vanadium. Ces complexes polymères de métaux de transition peuvent être des médiateurs du transfert d'électrons dans les détecteurs électrochimiques à base d'enzymes. Dans ce cas, les complexes de métaux de transition d'une part, acceptent les électrons arrivant des enzymes ou transfèrent les électrons aux enzymes, et ce à grande vitesse, et d'autre part, ils échangent rapidement des électrons avec le détecteur.

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