Process for preparing halogenated hydrocarbons

Details Process for preparing halogenated hydrocarbons Process for preparing halogenated hydrocarbons

C - Chemistry, Metallurgy

07

C

C07C 19/01 (2006.01) C07C 17/278 (2006.01)

Patent

CA 2238907

Halogenated hydrocarbons comprising at least 3 carbon atoms are obtained by reacting a haloalkane and a halogenated olefin in the presence of an organic compound of nickel as catalyst and, optionally, in the presence of a solvent. 1,1,1,3,3-pentachlorobutane can thus be obtained under mild conditions with a good yield.

Des hydrocarbures halogénés comprenant au moins 3 atomes de carbone sont obtenus par réaction entre un haloalcane et une oléfine halogénée en présence d'un composé organique du nickel comme catalyseur et, éventuellement, en présence d'un solvant. Le 1,1,1,3,3-pentachlorobutane peut ainsi être obtenu dans des conditions douces avec un bon rendement.

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